Pc Miler V 20 High Quality Crack Serial Free
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The presented polymerization-assisted assembly is flexible for fabricating large-area crack-free PCs on various substrates. The presented crack-free PCs also exhibit bendable and stretchable properties. The presented crack-free PCs also exhibit strong mechanical strength and resilience when bend and stretch. The reported crack-free PCs are also free of cracks in large areas.
Results and discussion
The colloidal spheres of poly(St-MMA-AA) are co-assembled on aluminium foil substrates. The colloidal spheres self-assemble into well-ordered periodic structures, and the monomer polymerizes in the interstices of the colloidal sphere to form a crosslinked elastomeric polymer network. The polymerization-assisted assembly is thus realized. The presented crack-free PCs are almost free of cracks in large areas as demonstrated by optical microscopy and scanning electron microscopy. The polymerization-assisted assembly is simple and flexible for fabricating large-area crack-free PCs. The presented crack-free PCs also exhibit bendable and stretchable properties.
The fabrication of large-area crack-free single crystalline PCs. The colloidal spheres of poly(St-MMA-AA) are self-assembled in a well-ordered manner onto a polyimide tape with a thickness of 200 μm. The monomer polymerizes in the interstices of the colloidal spheres to form a crosslinked elastic polymer network. The polymerization-assisted assembly is thus realized. The presented crack-free PCs are almost free of cracks in large areas as demonstrated by optical microscopy and scanning electron microscopy.
The monodispersity of the colloidal spheres with a polydispersity index of 0.005 and a special core-shell structure with a hydrophilic PAA shell and a hydrophobic PS core are favorable for the presented crack-free PCs. The good monodispersity of the colloidal spheres and the special core-shell structure are beneficial for the colloidal assembly into well-ordered periodic structures. Meanwhile, the hydrophilic PAA shell and the hydrophobic PS core can provide a good wetting environment for infiltration of the monomer, such as NIPAm and acrylamide, and thus induce the uniform infiltration. The high infiltration rate contributes to the formation of crack-free PCs.
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